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ESR of the reduction products of [Fe(bpy)3]2+ and [Ru(bpy)3]2+

✍ Scribed by Ann G. Motten; Kenneth Hanck; M.Keith DeArmound

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 548 KB
Volume: 79
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85032-4

No coin nor oath required. For personal study only.

✦ Synopsis

ESR of [Fe(bpy)3l+and

[ Ru(bpy)3]+suggests that the reduction electron IS located on a smgle hgand rather than delomhzed over dl three In solohon the electron hops from one Irgand to another. broadenmg the ESR hne In the trtply reduced jFe(bpy)s j-and 1 Ru(bpy), )-. one electron IS on each Itgsnd and there IS no hoppmg

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