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Equilibrium Conformations of Thiane 1-Oxide (Pentamethylene Sulfoxide)

✍ Scribed by Lambert, Joseph B.; Keske, Robert G.


Book ID
121404563
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
418 KB
Volume
31
Category
Article
ISSN
0022-3263

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The -C and 1 7 0 (~tural abundance) chemical shifts of several mono-and di-methyl ring-substituted thiane 1-oxides and thiane 1,l-dioxides are reported. The cis and trans isomers of methyl-substituted thiane l-oxide are readily identified by -C and 170 NMR. In particular, the "0 NMR signals of axial