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Calorimetric and Computational Study of Thiacyclohexane 1-Oxide and Thiacyclohexane 1,1-Dioxide (Thiane Sulfoxide and Thiane Sulfone). Enthalpies of Formation and the Energy of the SO Bond

✍ Scribed by Roux, María Victoria; Temprado, Manuel; Jiménez, Pilar; Dávalos, Juan Zenón; Notario, Rafael; Guzmán-Mejía, Ramón; Juaristi, Eusebio


Book ID
126938974
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
141 KB
Volume
68
Category
Article
ISSN
0022-3263

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A remarkable difference in the conformat
✍ L. Van Acker; M. Anteunis 📂 Article 📅 1974 🏛 Elsevier Science 🌐 French ⚖ 196 KB

The sulfoxide group shows a lot of interesting stereochemical features (2). In thiane-l-oxide the axial conformation (62% of the mixture at -9OOC) is favored by 175 Cal/mole (2). Introduction of a 3,3-dimethyl grouping reverses this axial