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Equilibrium acidities of 2-alkylthiazolium cations at the C-2.alpha. position

✍ Scribed by Bordwell, Frederick G.; Satish, A. V.; Jordan, Frank; Rios, Carlos B.; Chung, A. C.

Book ID
121384143
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
808 KB
Volume
112
Category
Article
ISSN
0002-7863

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## Abstract The title compounds 7 were prepared in situ by deprotection of the corresponding pivaloyl‐substituted oxetanes 3 with lithium aluminium hydride in tetrahydrofuran. under these conditions a reductive ring opening at c‐2 (hydrodealkoxylation) occurred which was initiated by a nucleophilic