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Hydroxyl-directed reductive ring opening at the C-2 position of functionalized 2-aryloxetanes

✍ Scribed by Thorsten Bach; Christian Lange


Book ID
103407011
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
117 KB
Volume
37
Category
Article
ISSN
0040-4039

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Regioselective Reductive Ring Opening of 2-(2-Hydroxyphenyl)-3-(( trimethylsilyl)oxy)oxetanes at the More Substituted C-2 Position. -The title compounds are prepared in situ by deprotection of the oxetanes (III) and (IV) with LiAlH4 in THF. Under these conditions a reductive ring opening occurs yiel