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ChemInform Abstract: Hydroxyl-Directed Reductive Ring Opening at the C-2 Position of Functionalized 2-Aryloxetanes.

✍ Scribed by T. BACH; C. LANGE

Book ID
112038559
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
27
Category
Article
ISSN
0931-7597

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Regioselective Reductive Ring Opening of 2-(2-Hydroxyphenyl)-3-(( trimethylsilyl)oxy)oxetanes at the More Substituted C-2 Position. -The title compounds are prepared in situ by deprotection of the oxetanes (III) and (IV) with LiAlH4 in THF. Under these conditions a reductive ring opening occurs yiel

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## Abstract The title compounds 7 were prepared in situ by deprotection of the corresponding pivaloyl‐substituted oxetanes 3 with lithium aluminium hydride in tetrahydrofuran. under these conditions a reductive ring opening at c‐2 (hydrodealkoxylation) occurred which was initiated by a nucleophilic