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Equilibrium Acidities and Homolytic Bond Dissociation Energies of N−H and/or O−H Bonds in N -Phenylhydroxylamine and Its Derivatives

✍ Scribed by Bordwell, Frederick G.; Liu, Wei-Zhong


Book ID
127303947
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
187 KB
Volume
118
Category
Article
ISSN
0002-7863

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Acidities and bond dissociation energies (BDEs) of the N-H bond in two phenylsulfenylamides, PhSNHBz and PhSNH-t-Bu, and four phenylsulfenylanilides, 4-GC 6 H 4 NHSPh, where G = MeO, H, Br and CN, were measured in order to compare the effects of substituents on acidities and BDEs of N-H bonds with t