ChemInform Abstract: Equilibrium Acidities and Homolytic Bond Dissociation Energies (BDEs) of the Acidic H—N Bonds in Hydrazines and Hydrazides.
✍ Scribed by Y. ZHAO; F. G. BORDWELL; J.-P. CHENG; D. WANG
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 24 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Acidities and bond dissociation energies (BDEs) of the N-H bond in two phenylsulfenylamides, PhSNHBz and PhSNH-t-Bu, and four phenylsulfenylanilides, 4-GC 6 H 4 NHSPh, where G = MeO, H, Br and CN, were measured in order to compare the effects of substituents on acidities and BDEs of N-H bonds with t
## Acidities of Stable Simple Enols and Bond Dissociation Enthalpies of Their H-O Bonds in DMSO. -The values of acidity and bond dissociation enthalpy of enols (I) are discussed in terms of steric and electronic effects. For the 1,1-dimesityl derivatives the pKHA values increase with the bulk of t
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