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EPR study of spin-trapped free radical intermediates formed in the heterogeneously-assisted photodecomposition of acetaldehyde †

✍ Scribed by Jenkins, Charles A.; Murphy, Damien M.; Rowlands, Christopher C.; Egerton, Terry A.

Book ID
121463014
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
122 KB
Volume
12
Category
Article
ISSN
1472-779X

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EPR/Spin-trapping study of free radical
EPR/Spin-trapping study of free radical intermediates in the photolysis of trifluoromethyl ketones with initiators
✍ Esmeralda Rosa; Angel Guerrero; Mª Pilar Bosch; Luis Julià 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 409 KB

## Abstract Photolysis of trifluoromethyl ketones (TFMKs) 1a–1e __versus__ the non‐fluorinated ketones 2a–2b in the presence of radical initiators by electron paramagnetic resonance spectroscopy has been studied for the first time. The transient radicals generated after irradiation of the ketones w