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Spin trapping of the short-lived free radicals formed in γ-irradiated alcohols

✍ Scribed by M. Shiotani; S. Murabayashi; J. Sohma


Publisher
Elsevier Science
Year
1976
Weight
830 KB
Volume
8
Category
Article
ISSN
0020-7055

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Electron paramagnetic resonance studies
✍ S.W. Mao; Larry Kevan 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 295 KB

The primary neutral radicals in y-irradiated liquid methanol at 194°K have been spin trapped with phenyl-t-butyl nitrone. The principal primary radicals are CH20H and CH30. In contrast to earlier work, these radicals are formed with an initial ratio of CHzCH/CHaO J 1.5 which agrees with gas phase ma