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Electron paramagnetic resonance studies of spin trapping of the primary neutral radicals formed in γ-irradiated methanol

✍ Scribed by S.W. Mao; Larry Kevan

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
295 KB
Volume
24
Category
Article
ISSN
0009-2614

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✦ Synopsis

The primary neutral radicals in y-irradiated liquid methanol at 194°K have been spin trapped with phenyl-t-butyl nitrone. The principal primary radicals are CH20H and CH30. In contrast to earlier work, these radicals are formed with an initial ratio of CHzCH/CHaO J 1.5 which agrees with gas phase mass spectrometric results. H atoms are also suin tIaDDed althouEh their aDDarent vieId is several times lower than that of the other radicals. In methanol glass at

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## Abstract The behavior of the methyl radical adduct of six β‐phosphorylated nitrones in the __N__‐benzylidene‐1‐diethoxyphosphoryl‐1‐methylethylamine N‐oxide series in the presence of sodium dodecyl sulfate (SDS) micelles was followed by electron paramagnetic resonance spectroscopy. Except when t