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EPR spin trapping of an oxalate-derived free radical in the oxalate decarboxylase reaction

✍ Scribed by Witcha Imaram; Benjamin T. Saylor; Christopher P. Centonze; Nigel G.J. Richards; Alexander Angerhofer

Book ID
113631943
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
780 KB
Volume
50
Category
Article
ISSN
0891-5849

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EPR/Spin-trapping study of free radical
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✍ Esmeralda Rosa; Angel Guerrero; MΒͺ Pilar Bosch; Luis JuliΓ  πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 409 KB

## Abstract Photolysis of trifluoromethyl ketones (TFMKs) 1a–1e __versus__ the non‐fluorinated ketones 2a–2b in the presence of radical initiators by electron paramagnetic resonance spectroscopy has been studied for the first time. The transient radicals generated after irradiation of the ketones w