dicted rate constants are invariably dominated by a 'Reaction with N'). While AOP treats amides as amines, we expect amides to be less reactive than amines from the analogous relationship between esters and ethers (see [3] for OH rate constants): if amines are matched to ethers (both are highly reac
EPR determination of absolute rate constants for the reactions of h and oh radicals with hydrogen bromide
β Scribed by J.L. Jourdain; G. Le Bras; J. Combourieu
- Book ID
- 107732801
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 500 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
Relative rate constants for the reactions of hydroxyl radicals with a series of alkyl substituted olefins were measured by competitive reactions between pairs of olefins a t 298 r 2 K and 1 atmospheric pressure. Hydroxyl radicals were produced by the photolysis of H,O, with 254-nm irradiation. The o
The kinetics of the reactions of hydroxy radicals with cyclopropane and cyclobutane has been investigated in the temperature range of 298-492 K with laser flash photolysidresonance fluorescence technique. The temperature dependence of the rate constants is given by k l = (1.17 ? 0.15) x T3'' exp[-(1