Epoxide Migration and Pseudo-Epoxide Migration of 1,6:2,3- and 1,6:3,4-Dianhydro-β-D-hexopyranoses. Synthesis of Some Deoxy Halo Derivatives of 1,6-Anhydro-β-D-hexopyranoses
✍ Scribed by Džoganová, Martina; Černý, Miloslav; Buděšínský, Miloš; Dračínský, Martin; Trnka, Tomáš
- Book ID
- 120165488
- Publisher
- UOCHB
- Year
- 2006
- Tongue
- English
- Weight
- 169 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0010-0765
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The synthesis of the isomeric 1,6-anhydro-3-0-benzyl-2-deoxy-2,4-di-Cmethyl-P-D-hexopyranoses and their spectral characterisation are described. 1,6-Anhydro-3-O-benzyl-2-deoxy-4-O-mesyl-2,4-di-C-methyl-~-D-galactopyranose undergoes ring-contraction on solvolysis.