The synthesis of the isomeric 1,6-anhydro-3-0-benzyl-2-deoxy-2,4-di-Cmethyl-P-D-hexopyranoses and their spectral characterisation are described. 1,6-Anhydro-3-O-benzyl-2-deoxy-4-O-mesyl-2,4-di-C-methyl-~-D-galactopyranose undergoes ring-contraction on solvolysis.
✦ LIBER ✦
1,6-Anhydro-4-O-benzyl-3-deoxy-2-O-methyl-β-d-ribo-hexopyranose and 1,6-Anhydro-4-O-benzyl-2-C-(2-cyanoethyl)-2,3-dideoxy-β-d-ribo-hexopyranose
✍ Scribed by Gainsford, G. J. ;Furneaux, R. H. ;Mason, J. M. ;Tyler, P. C.
- Book ID
- 114512264
- Publisher
- International Union of Crystallography
- Year
- 1995
- Tongue
- English
- Weight
- 396 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
1,6-anhydro-3-O-benzyl-2-deoxy-2,4-di-C-
✍
Alexander F. Sviridov; Michael S. Ermolenko; Dmitry V. Yashunsky; Alexander S. S
📂
Article
📅
1985
🏛
Elsevier Science
🌐
English
⚖ 1020 KB
Crystalline 3-Deoxy-α-D-ribo-hexose. Pre
✍
Pratt, James W.; Richtmyer, Nelson K.
📂
Article
📅
1957
🏛
American Chemical Society
🌐
English
⚖ 564 KB
ChemInform Abstract: Syntheses and React
✍
Jun Ning; Fanzuo Kong
📂
Article
📅
2001
🏛
John Wiley and Sons
⚖ 44 KB
👁 2 views
Synthesis and NMR Spectra of 1,6-Anhydro
✍
Karban, Jindřich; Buděšínský, Miloš; Černý, Miloslav; Trnka, Tomáš
📂
Article
📅
2001
🏛
UOCHB
🌐
English
⚖ 153 KB
Electrophile-mediated cyclizations of 6-
✍
Fillmore Freeman; Kirk D. Robarge
📂
Article
📅
1985
🏛
Elsevier Science
🌐
English
⚖ 633 KB
## Electrophile (bromine, iodine, mercuric acetate, mercuric trifluoroacetate, phenylselenyl chloride)-mediated cyclization of 6-0-benzyl-1,2-dideoxy-3,4-0isopropylidene-D-ribo-hex-l-enitol (2) led exclusively to l-substituted derivatives of 2,5-anhydro-6-0-benzyl-3,4-O-isopropylidene-D-altro-hex
Crystal structures of analogues of 3,1'-
✍
Foces-Foces, C. ;Smith-Verdier, P. ;Florencio-Sabate, F. ;García-Blanco, S.
📂
Article
📅
1975
🏛
International Union of Crystallography
⚖ 530 KB