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1,6-anhydro-3-O-benzyl-2-deoxy-2,4-di-C-methyl-β-d-hexopyranoses: Synthesis and properties

✍ Scribed by Alexander F. Sviridov; Michael S. Ermolenko; Dmitry V. Yashunsky; Alexander S. Shashkov; Nikolay K. Kochetkov

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 1020 KB
Volume: 136
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(85)85189-2

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✦ Synopsis

The synthesis of the isomeric 1,6-anhydro-3-0-benzyl-2-deoxy-2,4-di-Cmethyl-P-D-hexopyranoses and their spectral characterisation are described. 1,6-Anhydro-3-O-benzyl-2-deoxy-4-O-mesyl-2,4-di-C-methyl-~-D-galactopyranose undergoes ring-contraction on solvolysis.

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