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Enzymic synthesis of 2-keto-3-deoxy-8-phosphooctonic acid from ribose-5-phosphate and phosphoenolpyruvate

✍ Scribed by Daniel H. Levin; Efraim Racker


Book ID
118842612
Publisher
Elsevier Science
Year
1959
Tongue
English
Weight
293 KB
Volume
79
Category
Article
ISSN
0003-9861

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Synthesis of 2-deoxy-3,5-di-O-benzoyl-2,
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The title compound 2-Deoxy-3,5-di-O-benzoyl-2,2-difluoro-D-ribose (17), was synthesised from D-glucose and from D-mannose. The key steps of the synthesis from D-glucose are obtaining the 3,3-difluoropyranose 9 by reacting the ulose 7 with DAST. and their conversion into the difluorofuranoside 17 by