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Enzymatic oxidative coupling of monohalogenated tyrosine derivatives

โœ Scribed by You-An Ma; Zhi-Wei Guo; Charles J. Sih

Book ID
108387218
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
231 KB
Volume
39
Category
Article
ISSN
0040-4039

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Mechanism of thyroid hormone biosynthesi
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โœ You-An Ma; Charles J. Sih ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 248 KB

Both enzymatic and non-enzymatic oxidative coupling of 3,5-diiodo-L-tyrosine derivatives afforded a T4 derivative and a C3 fragment. The C3 fragment is not dehydroalanine as was claimed by previous workers but rather it was identified as aminomalonic semialdehyde, which decomposed to hydroxypyruvate