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Enzymatic oxidative coupling of hydroxyphenylglycine derivatives

โœ Scribed by Zhi-Wei Guo; Koji Machiya; You-An Ma; Charles J. Sih


Book ID
104259601
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
204 KB
Volume
39
Category
Article
ISSN
0040-4039

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Both enzymatic and non-enzymatic oxidative coupling of 3,5-diiodo-L-tyrosine derivatives afforded a T4 derivative and a C3 fragment. The C3 fragment is not dehydroalanine as was claimed by previous workers but rather it was identified as aminomalonic semialdehyde, which decomposed to hydroxypyruvate