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Enthalpy of association of carboxylic acids with pyridine and dimethyl sulfoxide

โœ Scribed by S. E. Odinokov; A. V. Iogansen

Publisher
Springer US
Year
1971
Tongue
English
Weight
388 KB
Volume
14
Category
Article
ISSN
0021-9037

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Desulfuration of Thio-Acids with Dimethy
Desulfuration of Thio-Acids with Dimethyl Sulfoxide
โœ Dr. M. Mikoล‚ajczyk ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 103 KB

Chlorinated cis-2,4-pentadienoyl chlorides (1) with R = H or CsHs and R' = CI react in the same way but more slowly (reaction time: 4 days). Ci2H2s C14Hz9 Ci6H13 Ci8H37 Benzyl Cyclohexyl Phenyl Monothioacetic acid is also desulfurated by dimethyl sulfoxide; the yield is 70% after one week at 2OoC.