Catalytic reduction of dimethyl sulfoxide and other sulfoxides with bromine - hydrobromic acid system.
β Scribed by Tetsuo Aida; Naomichi Furukawa; Shigeru Oae
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 187 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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The reduction of methionine sulfoxide with ammonium iodide in trifluoroacetic acid has been studied in peptides containing cysteine, histidine, tyrosine or tryptophan residues. While histidine and tyrosine have proved to be stable under the experimental conditions, cysteine is oxidized to cystine an
The kinetics of dimethyl sulfoxide (DMSO) oxidation by peroxomonophosphoric acid (PMPA) in aqueous medium a t 308 K and I = 0.4 mol/dm3 follow the rate expressions In the pH range from 0 to 2, where k l and kz are 5.092 X 10-1 dm3/mol sec and = 0, respectively; in the pH range from 4 to 7, where k2