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Energy transfer in Br +-Kr collisions

โœ Scribed by K. Balasubramanian; Joyce J. Kaufman; P.C. Hariharan; Walter S. Koski

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
538 KB
Volume
129
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

In the collision of Br + with Kr there is considerable transfer of translational to electronic energy and vice versa. This energy transfer is modelled as a Landau-Zener process at the points where the potential energy curves of the various electronic states of the halogen positive ion complex (KrBr 3 cross. Experimental transitions among the spin-orbit states of Br+ (viz. 'Dz +"jPo,,) are observed but all attempts to produce 'Dz+ 3Pr have failed. Relativistic CI calculations of lowlying states of KrBr+ have been carried out to explain the above experimental observations.

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