In the collision of Br + with Kr there is considerable transfer of translational to electronic energy and vice versa. This energy transfer is modelled as a Landau-Zener process at the points where the potential energy curves of the various electronic states of the halogen positive ion complex (KrBr
Energy transfer in ammonia-dimer-helium collisions
✍ Scribed by Z. Bačić; U. Buck; H. Meyer; R. Schinke
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 528 KB
- Volume
- 125
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
In a crossed molecular beam experiment differential time-of-flight spectra have been measured for (NH,),
- He collisions at E = 108 meV. The energy transfer in the backward direction is large. AE/E = 0.60. Only about half of it can be explained by simple rotational-vibrational excitation of the dimer without incorporating the internal degrees of freedom of each individual monomer.
📜 SIMILAR VOLUMES
Vibrational relaxation in Dz-Kr and D a-Kr-He mivtures has been measured behind incident shock waves in the temperatUre range 1400-3500"K, and VahIes 0fPrD2\_\_He, the vibrational relaxation time of Dt infinitely dilute in one atmosphere pressure of He, are derived. These values are compared with ca
Transfer of one quantum of vibrational excitation from a CO molecule initizlly in vibrational Iwel 1G to another CO mofecul~ inSalty in its ground vibrational level, a process endothermic by about 236 cm -I, is explained by a second-order distortrd-tive Born calculation. The distortion potent&l is r