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Energy transfer in ammonia-dimer-helium collisions

✍ Scribed by Z. Bačić; U. Buck; H. Meyer; R. Schinke


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
528 KB
Volume
125
Category
Article
ISSN
0009-2614

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✦ Synopsis


In a crossed molecular beam experiment differential time-of-flight spectra have been measured for (NH,),

  • He collisions at E = 108 meV. The energy transfer in the backward direction is large. AE/E = 0.60. Only about half of it can be explained by simple rotational-vibrational excitation of the dimer without incorporating the internal degrees of freedom of each individual monomer.

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