𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Energy partitioning and reaction dynamics in the chemiluminescent channel of the reaction: HS + O3 → HSO* + O2

✍ Scribed by D.J.W. Kendall; J.J.A. O'Brien; J.J. Sloan; R.Glen Macdonald

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
729 KB
Volume
110
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The title reaction fomls electronically excited HSO6 'A') directly, with considerable vibrational and rotational escitarion as well. The inrernal excitation of the HSO fragment is the maGrnum possible consistent with the concurrenr formation of an O~('A$ molecule as rhc other reaction product. The observed vibrational excitation peaks in rhe U' = 2 level of the ~3 mode. No cvidcncc about possible escitstion of the other vibrxtion7-l modes of HSO could bc obtained.

📜 SIMILAR VOLUMES

Chemiluminescent reaction at thermal ene
Chemiluminescent reaction at thermal energy: Vibrational distribution of CO+(A 2Π) from the C+ O2 reaction
✍ Masaharu Tsuji; Toshihiko Susuki; Minoru Endoh; Yukio Nishimura 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 280 KB

CO\*(A "ll-X 2P) emission produced from the C(2P) + O2 reaclm hss been observed al thermal cncrgy III a flowing afterdow apparatus. The relabve vIbrational population In the CO\*(A %I) state was dctcrrnmcd The avcngc fmctlon of VIbntional cncrgy dwrbulcd m CO+(A Zn).(/vJ. ws estimated to be 0.20 i 0

Energy dependence of the chemiluminescen
Energy dependence of the chemiluminescent Ba(6s5d 1D2)+O2→BaO*+O reaction
✍ J.M. Mestdagh; P. Meynadier; P. de Pujo; O. Sublemontier; J.P. Visticot; C. Alca 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 524 KB

The internal energy of the excited BaO formed in the reaction between Ba(6s5d 'D2) and an OZ molecule has been studied in a crossed beam apparatus as a function of the collision energy. It is found to be statistically distributed even at a collision energy as high as 0.58 eV. By comparison with the

Collision complex formation in the low-e
Collision complex formation in the low-energy dynamics of the C+ + O2 reaction
✍ D.M. Sonnenfroh; J.M. Farrar 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 645 KB

A crossed beam study of CO+ production from the C+ + 0s reaction at a collision energy of 0.57 eV is presented. Very clear collision complex dynamics are observed which are shown to be consistent with the decay of a transient complex having a lifetime of approximately 0.5 ps. An analysis of the reac

Chemiluminescent spectra of HNO and DNO
Chemiluminescent spectra of HNO and DNO in the reaction of O(3P)/O2 with NO and hydrocarbons of aldehydes
✍ T. Ishiwata; H. Akimoto; I. Tanaka 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 315 KB

The chemiluminescent emission from the electronically encited state of HNO ('A") was observed in the r&&ions of O$P)/O, with NO ard one oracetylene, ethylene, propylene, formaldehyde and acetaldehyde. The identification of the emitting species WS'BS confirmed by observing the emission from DNO ti th

Constant energy partitioning in the phot
Constant energy partitioning in the photoionization of NO and O2
✍ G.M. Lawrence 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 420 KB

Pub~~ed dz~ta on the photoclectmn spectra of NO and 02 ax analyzed, and the energy distributions are found to have averages proportional to the available energy. Hence, vibration rakes a corm=-urtrnction ofthccncrgy. Average distibwions are found CG nfunction of the fraction ofnvdl&ieencr=y.