Energy Barriers to Rotation in Axially Chiral Analogues of 4-(Dimethylamino)pyridine
β Scribed by Spivey, Alan C.; Charbonneau, Patrick; Fekner, Tomasz; Hochmuth, Detlev H.; Maddaford, Adrian; Malardier-Jugroot, Cecile; Redgrave, Alison J.; Whitehead, Michael A.
- Book ID
- 125511228
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 648 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract The free energy of activation for rotation about the exocyclic Cο£ΏN bond of the dimethylamino group of some 6βsubstituted 2βaminoβ4β(__N__,__N__βdimethylamino)pyrmidines has been determined using ^1^H NMR line shape analysis. The results are discussed in terms of the relative electronβwi
1997 stereochemistry stereochemistry (general, optical resolution) O 0030 20 -034 Effective Kinetic Resolution of Secondary Alcohols with a Planar-Chiral Analogue of 4-(Dimethylamino)pyridine. Use of the Fe(C5Ph5) Group in Asymmetric Catalysis. -The stereoselectivity displayed by the shown catalyst