✦ LIBER ✦
ChemInform Abstract: Effective Kinetic Resolution of Secondary Alcohols with a Planar- Chiral Analogue of 4-(Dimethylamino)pyridine. Use of the Fe(C5Ph5) Group in Asymmetric Catalysis.
✍ Scribed by J. C. RUBLE; H. A. LATHAM; G. C. FU
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
1997 stereochemistry stereochemistry (general, optical resolution) O 0030 20 -034 Effective Kinetic Resolution of Secondary Alcohols with a Planar-Chiral Analogue of 4-(Dimethylamino)pyridine. Use of the Fe(C5Ph5) Group in Asymmetric Catalysis.
-The stereoselectivity displayed by the shown catalyst is attributable in large part to the η5-C5Ph5 group and demonstrates for the first time that an increase in the steric bulk of a remote cyclopentadienyl ring can lead to an improvement in enantioselectivity. -(RUBLE,