Energetics of Iodine Ate Complexes, Intermediates in the Iodine/Magnesium Exchange on 1,1-Diiodoalkanes
✍ Scribed by Müller, Michael; Brönstrup, Mark; Knopff, Oliver; Schulze, Volker; Hoffmann, Reinhard W.
- Book ID
- 126302520
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 140 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
a-Lithionitriles add to benzynes to give N-lithiobenzocyclobutenamines in a two-step process. The intermediate aryllithiums can be trapped prior to cyclization with iodobenzene or 2,6-dimethoxyiodobenzene to form iodine-ate complex intermediates which fragment preferentially to 2-(a-cyanobenzyl)iodo
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