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α-Iodoalkyl–Iodine–Ate Complexes as Observable Intermediates in the Iodine– Magnesium Exchange Reaction

✍ Scribed by Volker Schulze; Mark Brönstrup; Volker P. W. Böhm; Peter Schwerdtfeger; Michael Schimeczek; Reinhard W. Hoffmann

Book ID
101301198
Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
98 KB
Volume
37
Category
Article
ISSN
0044-8249

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Iodine ate complexes and N-lithiobenzocy
Iodine ate complexes and N-lithiobenzocyclobutenamine intermediates in the reactions of α-lithionitriles with benzyne
✍ Sasmita Tripathy; Helmi Hussain; Tony Durst 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 100 KB

a-Lithionitriles add to benzynes to give N-lithiobenzocyclobutenamines in a two-step process. The intermediate aryllithiums can be trapped prior to cyclization with iodobenzene or 2,6-dimethoxyiodobenzene to form iodine-ate complex intermediates which fragment preferentially to 2-(a-cyanobenzyl)iodo