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Chiral Organometallic Reagents, XI. Stereoselective Exchange of Diastereotopic Iodine Atoms by Magnesium in 3-Alkoxy-1,1-diiodoalkanes

✍ Scribed by Hoffmann, Reinbard W. ;Kusche, Andreas


Publisher
Wiley (John Wiley & Sons)
Year
1994
Tongue
English
Weight
698 KB
Volume
127
Category
Article
ISSN
0009-2940

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Chiral Organometallic Reagents, I Stereo
✍ Hoffmann, Reinhard W. ;Bewersdorf, Martin ;Kr üger, Michael ;Mikolaiski, Wolfgan 📂 Article 📅 1991 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 999 KB

Bromine-lithium exchange in l,l-dibromo-3-(trimethylsilyl-silylating agents. Diastereoselectivity in the generation and oxy)alkanes 4 and 6 affords the carbenoids 8 and 14, which trapping of the carbenoids ranged between 70 -90% for 8 and have been added to ketones, aldehydes, arylboronates, and >90