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Energetics and mechanism of the thermal decarboxylation of tetracarbonyl(carboxy)ferrate(1-) in the gas phase

✍ Scribed by Sunderlin, L. S.; Squires, Robert R.


Book ID
126914048
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
914 KB
Volume
115
Category
Article
ISSN
0002-7863

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Thermal Decomposition of 1,2-Oxathiolane
✍ Carlsen, Lars ;Egsgaard, Helge πŸ“‚ Article πŸ“… 1984 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 293 KB πŸ‘ 2 views

## Abstract The cyclic sulfenic ester 1,2‐oxathiolane (**1**) decomposes thermally (400 – 450 K) exclusively to give acrolein (**3**) __via__ 3‐mercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2‐oxathiolane‐thietane 1‐oxide equilibrium