The thermal gas-phase reaction of CF,OF with CCI,CC12 h a s been studied between 313.8 a n d 343 8 K The initial pressure of CF,OF was varied between 10.8 a n d 77.5 torr a n d that of CCI;,CCI, between 3.7 a n d 26 8 torr. CF,OF was always present in excess, varying t h e initial ratio of CF,OF t o
Kinetics and mechanism of the thermal chlorination of chloroform in the gas phase
โ Scribed by G. Huybrechts; Y. Hubin; B. Van Mele
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 135 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The gas-phase pyrolysis of 3-chloroquadricyclane [1] was investigated over the temperature range 513-550 K at one atm in helium. The initial pyrolysis step is the isomerization of 3-chloroquadricyclane to 7-chloronorbornadiene (E ฯญ 39.63 ฯฎ 1.40 kcal/mole, a 7-chloronorbornadiene rearranges (623-660
2-Phenylethanol, racemic 1-phenyl-2-propanol, and 2-methyl-1-phenyl-2-propanol have been pyrolyzed in a static system over the temperature range 449.3-490.6ะC and pressure range 65-198 torr. The decomposition reactions of these alcohols in seasoned vessels are homogeneous, unimolecular, and follow a
The gas-phase elimination kinetics of primary, secondary and tertiary b-hydroxynitriles were examined in static seasoned vessels over the temperature range 360-450 ยฐC and pressure range 47-167 Torr (1 Torr = 133.3 Pa). These reactions are homogeneous, unimolecular and follow a first-order rate law.
DL-Mandelic acid was pyrolyzed in a static reaction vessel over the temperature range 300โข1-340โข0 ยฐC and pressure range of the substrate 15โข2-52โข1 Torr. The reaction, in a seasoned vessel and in the presence of the free radical inhibitor cyclohexene, is homogeneous, unimolecular and obeys a first-or