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Kinetics and mechanism of the gas-phase elimination of primary, secondary and tertiary 2-acetoxycarboxylic acids

โœ Scribed by Gabriel Chuchani; Rosa M Dominguez; Armando Herize; Roman Romero


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
86 KB
Volume
13
Category
Article
ISSN
0894-3230

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๐Ÿ“œ SIMILAR VOLUMES


The kinetics and mechanisms of gas phase
โœ Gabriel Chuchani; Alexandra Rotinov; Rosa M. Dominguez ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 149 KB ๐Ÿ‘ 1 views

2-Phenylethanol, racemic 1-phenyl-2-propanol, and 2-methyl-1-phenyl-2-propanol have been pyrolyzed in a static system over the temperature range 449.3-490.6ะŠC and pressure range 65-198 torr. The decomposition reactions of these alcohols in seasoned vessels are homogeneous, unimolecular, and follow a

Pyrolysis kinetics of 2-phenoxycarboxyli
โœ Gabriel Chuchani; Rosa M. Dominguez; Alexandra Rotinov; Ignacio Martin ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 67 KB ๐Ÿ‘ 2 views

The gas-phase pyrolysis kinetics of primary, secondary and tertiary 2-phenoxycarboxylic acids were studied over the temperature range 240.1-409.9 ยฐC and pressure range 16.3-67.8 Torr. The elimination reactions, carried out in seasoned vessels and in the presence of the free radical chain inhibitor c

Elimination kinetics of ฮฒ-hydroxynitrile
โœ Gabriel Chuchani; Rosa M. Dominguez; Alexandra Rotinov; Jairo Quijano; Cristina ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 63 KB

The gas-phase elimination kinetics of primary, secondary and tertiary b-hydroxynitriles were examined in static seasoned vessels over the temperature range 360-450 ยฐC and pressure range 47-167 Torr (1 Torr = 133.3 Pa). These reactions are homogeneous, unimolecular and follow a first-order rate law.

Kinetics and mechanism of thermal gas-ph
โœ Nouria A. Al-Awadi; Kamini Kaul; Osman M. E. El-Dusouqui ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 62 KB

2-Phenoxypropanoic acid together with five of its aryl derivatives, its phenylthio and its Nphenylamino analogues were pyrolyzed at 494-566 K. The reactions were homogeneous, polar and free from catalytic and radical pathways, and obeyed a first-order rate equation. The limits of the Arrhenius log A

ELIMINATION KINETICS OF DL -MANDELIC ACI
โœ Gabriel Chuchani; Ignacio Martin ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 42 KB ๐Ÿ‘ 1 views

DL-Mandelic acid was pyrolyzed in a static reaction vessel over the temperature range 300โ€ข1-340โ€ข0 ยฐC and pressure range of the substrate 15โ€ข2-52โ€ข1 Torr. The reaction, in a seasoned vessel and in the presence of the free radical inhibitor cyclohexene, is homogeneous, unimolecular and obeys a first-or