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Endor investigations on the capto-dative stabilisation of triphenylmethyl radicals

✍ Scribed by M. Lehnig; U. Stewen


Book ID
104232767
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
212 KB
Volume
30
Category
Article
ISSN
0040-4039

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Kinetics of the cis-trans isomerisation
✍ R MerΓ©nyi; A De Mesmaeker; H.G Viehe πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 196 KB

Capto-dative (cd) (c = CN, d = OR, SR, NR~) ccmpared to di-capto substitution (c = CN, c' = COOR) was found to be n-ore efficient in l-ring the activation energy of cis-trans isanerisation of cyclopropanes.