Kinetics of the cis-trans isomerisation of cyclopropanes : comparison between capto-dative and di-capto radical stabilisation

✍ Scribed by R Merényi; A De Mesmaeker; H.G Viehe

• Book ID: 104221368
• Publisher: Elsevier Science
• Year: 1983
• Tongue: French
• Weight: 196 KB
• Volume: 24
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)88016-8

✦ Synopsis

Capto-dative (cd) (c = CN, d = OR, SR, NR~) ccmpared to di-capto substitution (c = CN, c' = COOR) was found to be n-ore efficient in l-ring the activation energy of cis-trans isanerisation of cyclopropanes.