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Substituent effects on the formation of aminocarboxy-type capto-dative free radicals

✍ Scribed by Himmelsbach, Richard J.; Barone, Anthony D.; Kleyer, Don L.; Koch, Tad H.


Book ID
126854947
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
855 KB
Volume
48
Category
Article
ISSN
0022-3263

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Substituent effects on the CC bond stren
✍ ZΓΌffle, Stephan ;Beckhaus, Hans-Dieter ;RΓΌchardt, Christoph πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 370 KB

Products and kinetics of the homolytic thermolyses reactions of the three tertiary amides 6a-c of 2,3,3-triphenylpropanoic acid were studied in solution. The steric effects on the C-C bond homolysis processes were evaluated from MM2 calcu-lations. Taking this into account, we deduced radical stabili