Substituent effect of the carbonyl group on free-radical substitution. Bromination of adamantanone
β Scribed by Tabushi, Iwao; Aoyama, Yasuhiro; Yoshida, Zenichi
- Book ID
- 126815584
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 263 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0002-7863
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Gamma radiation-induced free radical chain reactions in liquid mixtures of BrCHpCN, cyclohexane (RH), and haloalkanes (XCC13) were studied. The kinetics of hydrogen and chlorine atom abstraction from CHC13, CH3CC13, CHzClCC13, CHClzCC13, CF3CC13, CpC16, CC13CN, and ccl4 by CHzCN radicals were invest
We have undertaken a study on the influence of three solvents on the photobromination of two picolines. It shows that dichloromethane and benzene are better solvents than the classical carbon tetrachloride. The obtention of a good free radical bromination is described using aqueous biphasic media.