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Enantiospecific syntheses of (3S,4R)- and (3S,4R,7S)-diastereoisomers of goniofufurone

✍ Scribed by Tony K.M. Shing; Hon-Chung Tsui


Book ID
103977059
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
429 KB
Volume
5
Category
Article
ISSN
0957-4166

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Enantiospecific synthesis of [7R,6S,5S,4
✍ G.S.C. Srikanth; Urlam MuraliKrishna; Girish K. Trivedi πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 75 KB

A short and efficient synthesis of [7R,6S,5S,4R]-triacetoxy-(-)-goniotriol starting form D-glucose is described. A sequence of ring closing metathesis (RCM) followed by a PCC oxidation was used to construct the core six-membered a,b-unsaturated lactone moiety.