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Enantioselective Total Synthesis of the Antitumor Macrolide Rhizoxin D

โœ Scribed by Lafontaine, Jennifer A.; Provencal, David P.; Gardelli, Cristina; Leahy, James W.

Book ID
111925980
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
415 KB
Volume
68
Category
Article
ISSN
0022-3263

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The enantioselective total synthesis of
The enantioselective total synthesis of the antitumor macrolide natural product rhizoxin D
โœ Jennifer A. Lafontaine; David P. Provencal; Cristina Gardelli; James W. Leahy ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 291 KB

A convergent, enantioselective total synthesis of rhizoxin D (didesepoxyrhizoxin), a potent antitumor natural product, was achieved via three critical olefinations, including a Horner-Emmons macrocyclization.