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Enantioselective Synthesis of Vinylcyclopropanes and Vinylepoxides Mediated by Camphor-Derived Sulfur Ylides: Rationale of Enantioselectivity, Scope, and Limitation

✍ Scribed by Deng, Xian-Ming; Cai, Ping; Ye, Song; Sun, Xiu-Li; Liao, Wei-Wei; Li, Kai; Tang, Yong; Wu, Yun-Dong; Dai, Li-Xin

Book ID: 121242294
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 486 KB
Volume: 128
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja056751o

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Scheme 1. Catalytic and asymmetric epoxidation of aldehydes; conditions: Rh 2 (OAc) 4 (1 mol %), BnEt 3 N + Cl À (10 mol %), CH 3 CN, 40 8C.