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Enantioselective Synthesis of Vinylcyclopropanes and Vinylepoxides Mediated by Camphor-Derived Sulfur Ylides: Rationale of Enantioselectivity, Scope, and Limitation.

✍ Scribed by Xian-Ming Deng; Ping Cai; Song Ye; Xiu-Li Sun; Wei-Wei Liao; Kai Li; Yong Tang; Yun-Dong Wu; Li-Xin Dai


Publisher
John Wiley and Sons
Year
2006
Weight
72 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Scheme 1. Catalytic and asymmetric epoxidation of aldehydes; conditions: Rh 2 (OAc) 4 (1 mol %), BnEt 3 N + Cl Γ€ (10 mol %), CH 3 CN, 40 8C.