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Sulfur-Ylide-Mediated Synthesis of Functionalized and Trisubstituted Epoxides with High Enantioselectivity; Application to the Synthesis of CDP-840

✍ Scribed by Varinder K. Aggarwal; Imhyuck Bae; Hee-Yoon Lee; Jeffery Richardson; David T. Williams

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 148 KB
Volume: 115
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200350968

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✦ Synopsis

Scheme 1. Catalytic and asymmetric epoxidation of aldehydes; conditions: Rh 2 (OAc) 4 (1 mol %), BnEt 3 N + Cl À (10 mol %), CH 3 CN, 40 8C.

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