Enantioselective synthesis of the top half of tetronolide
โ Scribed by William R. Roush; Kazuo Koyama
- Book ID
- 119482525
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- French
- Weight
- 264 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
An efficfent enanboseieciwe route to the actahydronaphlhabne uaf preseni II) tetronollde (I), the stereochem~calty complex aglycone common to the telrocarcms, a novel group of anlilumor substances, IS described The sequence employs the mtramolecular D/e/s-Aider reaction to control the relatrve stere
A highly ciiasfereoselective synthesis of the top ha/f (4) of kijanolide is described. The key step is fhe exo and diastereoface selective Die/s-Alder reaction of triene 6 and chiral dienophile 6.
The first enantioselective synthesis of a chlorothricolide intermediate is described. The synthesis features the intramolecular Diels-Alder reaction of tetraene 3.