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Enantioselective synthesis of (S)-(+)-2-tridecanol acetate, an aggregation pheromone component ofDrosophila mulleri

✍ Scribed by Enders, Dieter ;Plant, Andrew

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 321 KB
Volume: 1991
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.1991199101214

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✦ Synopsis

Abstract

The enantioselective synthesis of (S)‐(+)‐2‐tridecanol acetate [(S)‐6] (ee = 93.5%), an aggregation pheromone of Drosophila mulleri, is described. Key steps are the α‐alkylation of the propiophenone SAMP‐hydrazone (S)‐2 (de ≥ 96%) and the Baeyer‐Villiger reaction of the ketone (S)‐4.

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