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Enantioselective Synthesis of Isoindolines: An Organocatalyzed Domino Process Based On the aza-Morita–Baylis–Hillman Reaction

✍ Scribed by Dr. Shinobu Takizawa; Dr. Naohito Inoue; Shuichi Hirata; Prof. Dr. Hiroaki Sasai

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 407 KB
Volume: 122
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.201004547

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## Abstract A chiral BINOL‐based acid‐base catalyst is found to promote the aza‐Morita—Baylis—Hillman domino reaction of α,β‐unsaturated carbonyl compounds and N‐tosylimines to yield optically active tetrahydropyridines with good e.e.‐values.