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ChemInform Abstract: An Enantioselective Organocatalyzed Aza-MBH Domino Process: Application to the Facile Synthesis of Tetrahydropyridines.

✍ Scribed by Shinobu Takizawa; Naohito Inoue; Hiroaki Sasai

Publisher: John Wiley and Sons
Year: 2011
Weight: 42 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201116147

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✦ Synopsis

Abstract

A chiral BINOL‐based acid‐base catalyst is found to promote the aza‐Morita—Baylis—Hillman domino reaction of α,β‐unsaturated carbonyl compounds and N‐tosylimines to yield optically active tetrahydropyridines with good e.e.‐values.

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