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Enantioselective Synthesis of 4-Hydroxy-2-cyclohexenones through a Multicomponent Cyclization

✍ Scribed by Prof. Dr. José Barluenga; Dr. Marcos G. Suero; Raquel De la Campa; Dr. Josefa Flórez

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
344 KB
Volume
49
Category
Article
ISSN
0044-8249

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Asymmetric synthesis of (R) and (S)-4-hy
Asymmetric synthesis of (R) and (S)-4-hydroxy-2-cyclohexenone and derivatives
✍ M Carmen Carreño; José L García Ruano; Mercedes Garrido; M Pilar Ruiza; Guy Soll 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 293 KB

The arymmeti syntheses of both enantiomers of 4and O-benql derivatives are reported z4 DIBAL and ZnCl2/DI aTmy-2qciohewnone and their 0-acetyl L stemaelective reducrionr of the ketosulfaides resulting in the sul'nylation of Al-cyciohexanedione ethylene monoketai, are the key steps in these syntheses