Rhodium-Catalyzed Synthesis of Cyclohexenones via a Novel [4 + 2] Annulation.
β Scribed by Ken Tanaka; Gregory C. Fu
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The reaction mechanism of the Rhβcatalyzed [4 + 2] annulation of 4βalkynals with isocyanates is unraveled using density functional calculations. The reaction mechanisms of the model system and the real substituted system have been investigated and the results are compared. From our theo
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