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Enantioselective syntheses of the indole alkaloid (+)-R-decarbomethoxytetrahydrosecodine and its enantiomer

✍ Scribed by Mercedes Amat; Grigorii Pshenichnyi; Joan Bosch; Elies Molins; Carles Miravitlles

Book ID: 103977675
Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 240 KB
Volume: 7
Category: Article
ISSN: 0957-4166
DOI: 10.1016/0957-4166(96)00405-3

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✦ Synopsis

The alkaloid (+)-R-decarbomethoxytetrahydrosecodine (+)-1 has been synthesized by alkylation of (R)-3-ethylpiperidine with 3-(2-bromoethyl)-2ethylindole (7). The required enantiopurc piperidine was prepared by alkylation of the chiral non-racemic oxazolopiperidone (+)-trttns-.8 followed by reduction of the lactam

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