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ChemInform Abstract: Enantioselective Total Synthesis of the Indole Alkaloid 16-Episilicine.

✍ Scribed by Mercedes Amat; Begona Checa; Nuria Llor; Elies Molins; Joan Bosch

Publisher
John Wiley and Sons
Year
2009
Weight
28 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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The tetrahedrane framework with R=tBu and the octabisvalene framework with R = CH3 presumably form because of steric reasons. Whereas the hydrocarbon 2 is highly strained, the arrangement in 1 is largely strain-free, based on the intermolecular contact distances. With other residues R the occurrenc