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Synthesis, characterization and enantioselective free radical reductions of (1R,2S,5R)-menthyldiphenylgermane and its enantiomer

✍ Scribed by Le Zeng; Dainis Dakternieks; Andrew Duthie; Tamara Perchyonok; Carl Schiesser


Book ID
108283797
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
361 KB
Volume
15
Category
Article
ISSN
0957-4166

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## Abstract (βˆ’)‐Bicolorin [(1__S__,2__R__,5__R__)‐(βˆ’)‐2‐ethyl‐1,5‐dimethyl‐6,8‐dioxabicyclo[3.2.1]octane (1)], the male‐produced pheromone of __Taphrorychus bicolor__, and its (1__R__,2__R__,5__S__) isomer 2 were synthesized by starting from (__S__)‐limonene oxide (3), employing osmium tetroxide ca